J. Am. Chem. Soc. Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction
发布时间: 2017-03-13 浏览次数: 463

   近期,詹庄平教授课题组设计合成了一种新型的有机共轭多孔聚合物(CMP),将其与钯配位,该CMP基本结构单元“邻炔基吡啶”既是金属钯的配体也是载体,在Heck氧化反应中表现出极其优越的区域选择性,直链与支链产物比例最高可达>100:1ln/br> 100:1)。这一令人兴奋的研究成果表明有机共轭多孔聚合物的交联3D骨架具有调控区域选择性的作用,诱导出直链产物。

   相关工作由博士生周云兵等人完成,以Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction”为题在线发表于《美国化学会志》(Journal of the American Chemical Society, DOI: 10.1021/jacs.7b00643


Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction






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